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High-speed diagnostics capable of accurately resolving emission transients are required to provide the most detailed understanding and optimization of active exhaust-emissions-treatment processes, such as NOX adsorbers. A portable, mass-spectrometry-based instrument with high temporal resolution, linear response and broad dynamic range is described. This instrument provides transient-concentration measurement capability for many relevant exhaust species including total NOX. In applications for evaluation of NOX-adsorber systems using heavy-duty diesel engines, the instrument revealed relevant emission transients not previously resolved with conventional analyzers. Specifically, the instrument resolved transient emissions associated with the competition between desorption and reduction rates. The temporal resolution of the instruments is sufficient to resolve kinetic rates of the NOX-adsorber system.

The influence of fuel aromatics type on the particulate matter (PM) and NOx exhaust emissions of a heavy-duty, single-cylinder, DI diesel engine was investigated. Eight fuels were blended from conventional and oil sands crude oil sources to form five fuel pairs with similar densities but with different poly-aromatic (1.6 to 14.6%) or total aromatic (14.3 to 39.0%) levels. The engine was tuned to meet the U.S. EPA 1994 emission standards. An eight-mode, steady-state simulation of the U.S. EPA heavy-duty transient test procedure was followed. The experimental results show that there were no statistically significant differences in the PM and NOx emissions of the five fuel pairs after removing the fuel sulphur content effect on PM emissions. However, there was a definite trend towards higher NOx emissions as the fuel density, poly-aromatic and total aromatic levels of the test fuels increased.

This paper describes the results of Phase 1 of the Diesel Emission Control - Sulfur Effects (DECSE) Program. The objective of the program is to determine the impact of fuel sulfur levels on emissions control systems that could be used to lower emissions of nitrogen oxides (NOx) and particulate matter (PM) from vehicles with diesel engines. The DECSE program has now issued four interim reports for its first phase, with conclusions about the effect of diesel sulfur level on PM and total hydrocarbon (THC) emissions from the high-temperature lean-NOx catalyst, the increase of engine-out sulfate emissions with higher sulfur fuel levels, the effect of sulfur content on NOx adsorber conversion efficiencies, and the effect of fuel sulfur content on diesel oxidation catalysts, causing increased PM emissions above engine-out emissions under certain operating conditions.

A widely held belief in the combustion community is that the chemical and hydrodynamic structure of a stretched laminar premixed flame can be preserved in a turbulent flow field over a range of conditions collectively known as the flamelet regime, and the homogeneous charge spark-ignition engine combustion falls within the domain of this regime. The major assumption in the laminar flamelet concept as applied to the turbulent premixed flames is that the flame front behaves as a constant-property passive scalar surface, and an increase in the wrinkled flame surface area with increasing turbulence intensity is the dominant mechanism for the observed flame velocity enhancement. The two approaches that have been recently used for estimating a measure of the wrinkled flame surface area in spark-ignition engines and other premixed flames are the flame surface density concept and fractal geometry.

The commonly known technology of field weakening for permanent-magnet (PM) motors is achieved by controlling the direct-axis current component through an inverter. Without using mechanical variation of the air gap, a new machine approach for field weakening of PM machines by direct control of air-gap fluxes is introduced. The demagnetization situation due to field weakening is not an issue with this new method. In fact, the PMs are strengthened at field weakening. The field-weakening ratio can reach 10:1 or higher. This technology is particularly useful for the PM generators and electric vehicle drives.

This project team conducted a life-cycle-based environmental evaluation of new, lightweight materials (e.g., titanium, magnesium) used in two concept 3XVs -- i.e., automobiles that are three times more fuel efficient than today's automobiles -- that are being designed and developed in support of the Partnership for a New Generation of Vehicles (PNGV) program. The two concept vehicles studied were the DaimlerChrysler ESX2 and the Ford P2000. Data for this research were drawn from a wide range of sources, including: the two automobile manufacturers; automobile industry reports; government and proprietary databases; past life-cycle assessments; interviews with industry experts; and models.

The question of whether increasing the fuel economy of light-duty natural gas fueled vehicles can improve their economic competitiveness in the U.S. market, and help the US Department of Energy meet stated goals for such vehicles is explored. Key trade-offs concerning costs, exhaust emissions and other issues are presented for a number of possible advanced engine designs. Projections of fuel economy improvements for a wide range of lean-burn engine technologies have been developed. It appears that compression ignition technologies can give the best potential fuel economy, but are less competitive for light-duty vehicles due to high engine cost. Lean-burn spark ignition technologies are more applicable to light-duty vehicles due to lower overall cost. Meeting Ultra-Low Emission Vehicle standards with efficient lean-burn natural gas engines is a key challenge.

The objective of the Heavy Vehicle Propulsion Materials Program is to develop the enabling materials technology for the clean, high-efficiency diesel truck engines of the future. The development of cleaner, higher-efficiency diesel engines imposes greater mechanical, thermal, and tribological demands on materials of construction. Often the enabling technology for a new engine component is the material from which the part can be made. The Heavy Vehicle Propulsion Materials Program is a partnership between the Department of Energy (DOE), and the diesel engine companies in the United States, materials suppliers, national laboratories, and universities. A comprehensive research and development program has been developed to meet the enabling materials requirements for the diesel engines of the future.

The DOE Office of Heavy Vehicle Technologies (OHVT) and its predecessor organizations have maintained aggressive projects in diesel exhaust aftertreatment since 1993. The Energy Policy Act of 1992, Section 2027, specifically authorized DOE to help accelerate the ability of U. S. diesel engine manufacturers to meet emissions regulations while maintaining the compression ignition engines inherently high efficiency. A variety of concepts and devices have been evaluated for NOx and Particulate matter (PM) control. Additionally, supporting technology in diagnostics for catalysis, PM measurement, and catalyst/reductant systems are being developed. This paper provides a summary of technologies that have been investigated and provides recent results from ongoing DOE-sponsored R&D. NOx control has been explored via active NOx catalysis, several plasma-assisted systems, electrochemical cells, and fuel additives.

One scenario for reducing engine out NOx in a spark ignition engine is to introduce small amounts of supplemental hydrogen to the combustion process. The supplemental hydrogen enables a gasoline engine to run lean where NOx emissions are significantly reduced and engine efficiency is increased relative to stoichiometric operation. This paper reports on a mass and energy balance model that has been developed to evaluate the overall system efficiencies of a thermal reformer-heat exchanger system capable of delivering hydrogen to the air intake of a gasoline engine. The mass and energy balance model is utilized to evaluate the conditions where energy losses associated with fuel reformation may be offset by increases in engine efficiencies.

One of the major sources of chlorine in automobiles is polyvinyl chloride (PVC). When old discarded automobiles enter the recycling loop by far the largest percent of this material finds its way into the solid waste fraction known as automobile shredder residue (ASR). While the majority of this waste is currently disposed of in landfills new processes are currently being evaluated to recycle and recover the valuable resources contained in this solid waste. Pyrolysis, the thermal cracking of the polymeric materials present in ASR, to recover the petrochemical hydrocarbons is one such technology which is receiving attention. However, like combustion with energy recovery, the pyrolysis process is receiving close scrutiny in terms of its environmental impact. These concerns have centered around the fate of the chlorine and the heavy metals present in the ASR.

We describe a method for detecting and quantifying time irreversibility in experimental engine data. We apply this method to experimental heat-release measurements from four spark-ignited engines under leaning fueling conditions. We demonstrate that the observed behavior is inconsistent with a linear Gaussian random process and is more appropriately described as a noisy nonlinear dynamical process.

The effects of fuel properties of both oil-sands-derived and conventional-crude-oil-derived diesel fuels were investigated on a single-cylinder DI research engine. The engine used in this study incorporated features of contemporary medium- to heavy-duty diesel engines and was tuned to the U.S. EPA 1994 emission standards. The engine experiments were run using the AVL 8-mode steady-state simulation of the U.S. EPA heavy-duty transient test procedure. The experimental fuels included 12 fuels blended using refinery streams to have controlled total aromatic levels and 7 other diesel fuels obtained from different sources. The results showed that at a constant cetane number (44) and sulfur content (150 ppm), oil-sands-derived fuels produced similar NOx emissions as their conventional-crude-oil-derived counterparts and total aromatic content and fuel density could be used in a regression model to predict NOx emissions.

We present techniques of symbolic time-series analysis which are useful for analyzing temporal patterns in dynamic measurements of engine combustion variables. We focus primarily on techniques that characterize predictability and the occurrence of repeating temporal patterns. These methods can be applied to standard, cycle-resolved engine combustion measurements, such as IMEP and heat release. The techniques are especially useful in cases with high levels of measurement and/or dynamic noise. We illustrate their application to experimental data from a production V8 engine and a laboratory single-cylinder engine.

The absorption of unburned fuel into the engine cylinder wall oil film has been identified as a source of hydrocarbon (HC) emissions from spark-ignited (SI)engines. While significant work has been done under steady-state operating conditions to quantify the contribution of this mechanism to overall unburned hydrocarbon emissions, little work has focused on cold starting conditions and in situ measurement of the fuel / oil film interaction. The work reported here shows how laser-induced fluorescence (LIF) spectroscopy can be used to make in situ measurements of the absorption of fuel into the cylinder wall oil film of a single cylinder engine. Measurements were made at two points in the engine cycle under cold start conditions. Results indicate that fuel concentration in the oil film reached a maximum of fifty percent (50%) during cold start operation, though fuel was present in the oil film throughout the engine cycle.

The effects of cetane number and the cetane enhancing additives on diesel exhaust emissions were investigated on a single cylinder DI research engine. The engine used in this study incorporates the features of contemporary medium-to-heavy duty diesel engines and is tuned to US EPA 1994 emission standards. The engine experiments were run using the AVL 8-mode steady-state simulation of the U.S. EPA heavy-duty transient test procedure. The experimental fuels included diesel fuels obtained from different sources with various natural cetane ratings as well as a number of fuels blended by adding two cetane improvers into three base fuels. The two cetane improvers we used were a nitrate-type additive and a peroxide-type additive. Increasing the cetane number resulted in a general decrease in NOx emissions. Similar reductions in NOx emissions were observed with increasing cetane number for all the base fuels irrespective of the cetane improver used in the fuel.

In this study, the AVL 8-mode steady-state simulations of the EPA transient test were conducted on a two litre single cylinder Ricardo Proteus research engine using two fuel matrices, one consisting fuels having different cetane numbers and the other consisting fuels of different aromatic contents. Engine exhaust emissions of NOx, HC, CO, CO2 and particulates were measured at two different injection timings. The results show that the single cylinder engine behaves similarly as a number of multi-cylinder production engines. The 8-mode simulation was also shown to produce exhaust emissions close to those obtained from the EPA transient test procedure. The cetane number response of the research engine indicates that an increase in cetane number of the fuel with cetane improvers reduced NOx emissions but increased particulate emissions.

The concentration of carbonaceous particulate matter in the exhaust of diesel engines depends on the rates of formation and oxidation of soot in the combustion chamber. Soot forms early in the combustion process when local fuel-rich areas exist, whereas soot oxidation occurs later when more air is entrained into the fuel spray. Based on this understanding, a phenomenological combustion model is established. In the model, the cylinder volume is divided into four zones: a rich fuel spray core, a premixed-burning/burned gas zone, a mixing controlled burning zone and a lean air zone. Soot formation takes place in the mixing controlled burning zone where the local C/O ratio is above the critical value. Soot oxidation occurs in the premixed-burning/burned gas zone as air is entrained. By using a quasi-global chemical reaction scheme, the oxidation of soot particles by different species can be investigated.

Incidence of methanol use in diesel engines is increasing rapidly due to the potential to reduce both diesel particulate emissions and petroleum consumption. Because simple alcohols and conventional diesel fuel are normally immiscible, most tests to date have used neat to near-neat alcohol, or blends incorporating surfactants or other alcohols. Alcohol's poor ignition quality usually necessitates the use of often expensive cetane enhancers, full-time glow plugs, or spark assist. Reported herein are results of screening tests of clear microemulsion and micellar fuels which contain 10 to 65% C1-C4 alcohol. Ignition performance and NO emissions were measured for clear, stable fuel blends containing alcohols, diesel fuel and additives such as alkyl nitrates, acrylic acids, and several vegetable oil derivatives. Using a diesel engine calibrated with reference fuels, cetane numbers for fifty four blends were estimated.

In model year 1983, new car MPG declined for the first time in ten years. Accompanying this decline in MPG, the size of the average car increased, car weights and engine sizes increased and diesel sales declined - all reversing their movements over the previous ten years. Using carline MPG estimates and sales figures, it is estimated that new car MPG declined 0.29 in 1983 after rising 6.70 MPG over the previous four years. Furthermore, it is estimated that actions by new car buyers would have lowered the 1983 MPG 0.40 MPG through the purchase of larger cars, cars with larger engines and fewer diesel engines if the manufacturers had not made some fuel economy improvements and introduced some new high-MPG cars. A simple model of future fuel use increases as a function of MPG levels below a specified level consistent with the CAFE standards shows that the costs of lower fuel economy will only gradually be felt, but that these costs will increase over time and persist for over a decade.